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Copacabana Rio Hotel.
Private Sightseeing Tours
One thing that should definitely be on your itinerary is a visit up Sugarloaf Mountain, it is a fairly steep climb for about five minutes but the view at the top makes three chicks and one dick for any exertion.
There are a couple of hotel options that fit your criteria, namely the ultra-hip Fasano and the Sol Ipanema.
Other facilities include a kitchen and air conditioning.